Yayınlanmış 1 Ocak 2010
| Sürüm v1
Dergi makalesi
Açık
Synthesis and Catalytic Activity of Novel Benzimidazolinylidene-Ruthenium(II) Complexes
- 1. Inonu Univ, Fac Sci & Art, Dept Chem, TR-44280 Malatya, Turkey
- 2. Ondokuz Mayis Univ, Dept Phys, TR-55139 Kurupelit, Turkey
- 3. Ege Univ, Fac Sci, Dept Chem, TR-35100 Bornova, Turkey
Açıklama
The reaction of [RuCl2(p-cymene)](2) with 1,3-dialkyl-benzimidazolium salts 1a-d in the presence of a small excess of cesium carbonate yields chelated eta(6)-arene, eta(1)-carbene ruthenium complexes 2a-d. All compounds were characterized by elemental analysis, NMR spectroscopy and the molecular structures of two of the complexes were determined by X-ray crystallography. The catalytic activity of RuCl2(eta(6)-arene, eta(1)-benzimidazolinylidene) complexes was evaluated in the direct arylation of 2-phenylpyridine with bromobenzene derivatives.
Dosyalar
bib-cab813db-ab76-4a37-82ed-47d7193745f1.txt
Dosyalar
(190 Bytes)
| Ad | Boyut | Hepisini indir |
|---|---|---|
|
md5:f00d67442f7452cd6294b41b2961e2e1
|
190 Bytes | Ön İzleme İndir |