Published January 1, 2022 | Version v1
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Substituent effect on iron phthalocyanines as cyclohexene oxidation catalysts

  • 1. Gebze Tech Univ, Dept Chem Engn, TR-41400 Kocaeli, Turkey
  • 2. Marmara Univ, Fac Technol, Dept Met & Mat Engn, Istanbul, Turkey
  • 3. Gebze Tech Univ, Dept Chem, TR-41400 Kocaeli, Turkey

Description

The effect of electron withdrawing vs electron donating substituents on the catalytic activity of iron phthalocyanines was investigated using cyclohexene oxidation as a model reaction. We demonstrate that iron phthalocyanine with electron-withdrawing substitutents showed better conversion and selectivity into 2-cyclohexen-1-one (ON) oxidation products.

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