Published January 1, 2010
| Version v1
Journal article
Open
Computational Study of Factors Controlling the Boat and Chair Transition States of Ireland-Claisen Rearrangements
- 1. Bogazici Univ, Dept Chem, TR-34342 Istanbul, Turkey
- 2. Univ Calif Los Angeles, Dept Chem & Biochem, Los Angeles, CA 90095 USA
Description
The origins of the boat transition state preference in the Ireland-Claisen rearrangements Studied experimentally by Kishi and co-workers have been explored computationally with Density Functional Theory. Steric interactions in the chair transition states were identified as the principal reason for the boat transition state preference.
Files
bib-562cee78-13f7-4aa5-8348-fbb4e975945a.txt
Files
(220 Bytes)
| Name | Size | Download all |
|---|---|---|
|
md5:11e247fed8c2222371046419c8b093e7
|
220 Bytes | Preview Download |