Published January 1, 2021
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BODIPY-vinyl dibromides as triplet sensitisers for photodynamic therapy and triplet-triplet annihilation upconversion
Creators
- 1. Izmir Inst Technol, Fac Sci, Dept Chem, Izmir, Turkey
- 2. Izmir Katip Celebi Univ, Fac Pharm, Dept Analyt Chem, Izmir, Turkey
- 3. Natl Metrol Inst TUBITAK UME, Sci & Technol Res Council Turkey, Chem Grp, Organ Chem Lab, Kocaeli, Turkey
- 4. Dalian Univ Technol, Sch Chem Engn, State Key Lab Fine Chem, E 208 Western Campus,2 Ling Gong Rd, Dalian 116012, Peoples R China
- 5. Izmir Inst Technol, Fac Sci, Dept Photon, TR-35430 Izmir, Turkey
Description
We devised a new generation of halogen-based triplet sensitisers comprising geminal dibromides at the vinyl backbone of a BODIPY fluorophore. Incorporating geminal dibromides into the pi-conjugation of BODIPY enhanced intersystem crossing due to the heavy atom effect, which in turn improved the extent of excited triplet states.
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