Published January 1, 2021
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Synthesis, Molecular Structure, Biological Activity, and Sensor Properties of (E)-2-[(3,5-Bis(trifluoromethyl)phenylimino)methy1]-4,6-dichlorophenol
- 1. Turkish Atom Energy Commiss, Ankara Nucl Res & Training Ctr, TR-06100 Ankara, Turkey
- 2. Ankara Univ, Vocat Sch Hlth Serv, TR-06290 Ankara, Turkey
- 3. Canakkale Onsekiz Mart Univ, Fac Arts & Sci, Dept Biol, TR-17100 Canakkale, Turkey
- 4. Karabuk Univ, Dept Chem, Fac Sci, TR-78050 Karabuk, Turkey
- 5. Near East Univ, Ataturk Fac Educ, Mersin 10, Nicosia, Turkey
- 6. Ankara Univ, Fac Sci, Dept Phys, TR-06100 Ankara, Turkey
- 7. Canakkale Onsekiz Mart Univ, Fac Arts & Sci, Dept Chem, TR-17100 Canakkale, Turkey
Description
In the present study, a Schiff base (E)-24(3,5-bis(trifluoromethyl)phenylimino)methyl]-4,6-dichlorophenol has been synthesized. Its spectroscopic and X-ray single -crystal data have been compared with the results of theoretical calculations based on the DFT method, as well as molecular electrostatic potential (MEP), HOMO and LUMO, and nonlinear optical (NLO) effects Antimicrobial activity of the compound has been tested against some bacteria and fungi. According to UV-Vis and agarose gel electrophoresis methods, the compound interacts with DNA electrostatically and breaks it oxidatively. Antioxidant activity of the compound measured by the DPPH method, is lower than that of BHT.
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