Yayınlanmış 1 Ocak 2011 | Sürüm v1
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A new hydrogen-bonded pseudo-dimer Mn(III) Schiff base complex. The synthesis, X-ray structure and spectroscopic studies

  • 1. Balikesir Univ, Fac Sci & Art, Dept Phys, TR-10145 Balikesir, Turkey

Açıklama

A new hydrogen-bonded pseudo-dimer, [Mn(III)L1(CH3CH2OH)](2)(ClO4) (1) (L1 = N,N'-bis(2-hydroxy-1-naphthalidenato)-1,2-diaminopropane) has been synthesized and characterized by UV-vis, IR, elemental analysis and crystal structure analysis. The single crystal X-ray diffraction reveals that the structure affords an elongated octahedral MnN2O4 coordination environment, geometry with the four donor atoms of the tetradentate Schiff base in the equatorial plane and with two ethanol molecule in axial positions with Mn-O = 2.265(2) and 2.266(2) angstrom. (C) 2011 Elsevier B.V. All rights reserved.

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