Published January 1, 2011
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Tridentate ligands derived from L-tert-Leucine for the Cu(II) mediated asymmetric Henry reaction
- 1. Ege Univ, Dept Chem, Fac Sci, TR-35100 Izmir, Turkey
Description
Chiral tridentate Schiff base ligands were prepared from L-tert-Leucine and used as catalysts in the asymmetric Henry reaction in the presence of Cu(II) ions. Moderate enantiomeric excesses (up to 66%) and yields (up to 76%) of the desired beta-nitroalcohols were obtained.
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