Yayınlanmış 1 Ocak 2013
| Sürüm v1
Dergi makalesi
Açık
beta-Hydroxyamide derivatives of salicylic acid as organocatalysts for enantioselective reductions of prochiral ketones
- 1. Dicle Univ, Fac Sci, Dept Chem, TR-21280 Diyarbakir, Turkey
Açıklama
In order to find the most effective catalyst for the enantioselective reduction of a prochiral ketone, a series of novel beta-hydroxyamide derivatives of salicylic acid and chiral amino alcohols were synthesized. Different substituted prochiral ketones have been reduced in high yield (up to 99%) and the corresponding secondary alcohols are formed with good enantiomeric excess (up to 86%). The mechanism of this type of catalyst can be explained by considering the reaction mechanism for the CBS catalyst. (C) 2013 Elsevier Ltd. All rights reserved.
Dosyalar
bib-ce94b131-dfb5-4516-9be9-77640e3c3c76.txt
Dosyalar
(236 Bytes)
| Ad | Boyut | Hepisini indir |
|---|---|---|
|
md5:a1f0b5dff7c50f11135e2973d1e00b60
|
236 Bytes | Ön İzleme İndir |