Published January 1, 1995
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SYNTHESIS OF MACROAZOINIMERS AND THEIR USE IN VINYL POLYMERIZATION
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Macroazoinimers are macromonomer azoinitiators and have been prepared by the reaction of polyazoesters having polyethylene glycol units and a functionalized vinyl monomer. Macroazoinimers behave as a macroinimer, a macrocrosslinker and an initiator, so they can be homopolymerize as well as copolymerize with another vinyl monomer. In each case, polymerization reactions give cross-linked polymers. Polymerization conditions and properties of polymers obtained by using macroazoinimers have been studied.
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