Dergi makalesi Açık Erişim
Acikgoz, Sabriye; Yungevis, Hasan
Hexagonal prisms with hexagonal pyramid end of Ga(2)O(3)microstructures were successfully prepared on gallium arsenide substrate by double cell electrochemical etching method under various growth conditions. The field emission scanning electron microscopy, energy-dispersive X-ray spectroscopy, X-ray photoelectron spectroscopy (XPS), photoluminescence (PL) and fluorescence lifetime imaging microscopy (FLIM) were used to characterize the hexagonal prisms. The EDS analysis confirmed that the prepared prisms were composed dominantly of gallium (Ga) and oxygen (O) with atomic ratio of similar to 2:3. The binding energy of the Ga 2pand Ga 3dXPS peaks revealed that the formation of Ga-O bonding with the highest oxidation state of Ga (Ga3+) and the formed hexagonal microstructures were Ga2O3. The PL spectra at room temperature under excitation at 290 nm exhibit a strong blue emission peak located at about 470 nm. The origin of this PL peak can be attributed to exciton recombination at different intrinsic defect sites such as O vacancies and Ga vacancies. Moreover, FLIM technique has been employed to probe time-resolved photoluminescence properties of individual Ga(2)O(3)prisms with hexagonal tip. FLIM images provide two-dimensional spatial maps of the carrier recombination lifetime which considered the most critical parameter to improve the performance of optoelectronic devices. It has been concluded that the carrier recombination lifetime was strongly sensitive to the size of the hexagonal prism-shaped structures due to surface-related defects. Additionally, a quantitative analysis of a conjugate system prepared by functionalizing hexagonal Ga(2)O(3)prisms with perylene organic dye molecules was reported in this work. The size-dependent electronic coupling between the conduction band level of gallium oxide and excited states of perylene molecules was investigated. We observed that highly efficient electron transfer process occurs for aggregated molecules due to excimer trap states. The grown prism structures seem to be interesting for applications in optoelectronic devices as well as to be used as an effective host medium for organic dye molecules in solar cell applications.
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