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Synthesis of an F-BODIPY [2]catenane using the chemistry of bis(dipyrrinato) metal complexes

2017    Nisanci, Bilal; Sahinoglu, Sinem; Tuner, Esra; Arik, Mustafa; Kani, Ibrahim; Dastan, Arif; Bozdemir, Ozgur Altan

ML2 type complexes of an olefin terminated 5H-dipyrrin ligand can be subjected to twofold ring closing metathesis to give bis(dipyrrinato)copper(II) and bis(dipyrrinato) zinc(II) [2] catenates. Demetalation of the copper(II) [2] catenate with KCN/N2H4 center dot H2O gave the corresponding bis(dipyrrin) [2] catenand. The boron difluoride complex of this bis(dipyrrin) was obtained as the first fluorescent F-BODIPY [2] catenane.