Yayınlanmış 1 Ocak 2010 | Sürüm v1
Dergi makalesi Açık

New 3-vinylation products of indole and investigation of its Diels-Alder reactivity: synthesis of unusual Morita-Baylis-Hillman-type products

  • 1. Ataturk Univ, Fac Sci, Dept Chem, TR-25240 Erzurum, Turkey
  • 2. Giresun Univ, Fac Arts & Sci, Dept Chem, TR-28049 Giresun, Turkey

Açıklama

3-Vinylindoles as precursors of carbazole and bis-indole derivatives were synthesized. Then, to form new carbazoles, Diels-Alder reactivity of these vinylindoles was studied with various dienophiles. During the cycloaddition reaction, unusual Morita-Baylis-Hillman-type products were observed. The structure and the formation mechanism of the products is discussed. (C) 2010 Elsevier Ltd. All rights reserved.

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