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Ligand-bridged bicobaloximes synthesized by ligand replacement: Synthesis, structure and characterization

2013    Kumar, Sarvendra; Seidel, Ruediger W.

Two ligand-bridged bicobaloximes, formed by replacement of pyridine (py) in monocobaloximes, [MeCo(dmgH)(2)(PY)] (Me = methyl, dmgH = dimethylglyoxime) and MeCo(dpgH)(2)(pY) (dpgH = diphenylglyoxime), by 4,4'-bipyridine and 2,4-di(1H-imidazol-1-yl)-6-methoxy-1,3,5-triazine, respectively, are reported. The crystal structures of the ligand-bridged bicobaloximes so obtained are described. (C) 2012 Elsevier B.V. All rights reserved.