Published January 1, 2010
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Models for the basis of enantioselection in palladium mediated C-H activation reactions
- 1. Univ E Anglia, Sch Chem, Norwich NR4 7TJ, Norfolk, England
Description
Models are proposed to account for the basis of enantioselection in cyclopalladation reactions, which result in the formation of planar chiral palladacycles. This analysis is extended to a palladium catalysed enantioselective C-H activation reaction proceeding via the intermediacy of a chiral palladacycle. (C) 2010 Elsevier Ltd. All rights reserved.
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