Published January 1, 2022
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Nickel-catalyzed alkylation of ketones and nitriles with primary alcohols
- 1. Ege Univ, Dept Chem, TR-35100 Izmir, Turkey
Description
Nickel(ii)-salen or nickel(ii)-salphen catalyzed alpha-alkylation of ketones and nitriles with primary alcohols is reported. Various alpha-alkylated ketones and nitriles were obtained in high yields through a borrowing hydrogen strategy by using 1-3 mol% of nickel catalyst and a catalytic amount of NaOH (5-10 mol%) under aerobic conditions.
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