Published January 1, 2021 | Version v1
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Synthesis, photophysical, thermal properties and X-Ray studies of novel organic dyes bearing Inden-1-ylidene and fluorene

  • 1. Gazi Univ, Fac Sci, Dept Chem, TR-06560 Ankara, Turkey
  • 2. Univ Rennes, CNRS, UMR6226, Inst Sci Chim Rennes, F-35000 Rennes, France
  • 3. Univ Rennes 1, IUT Lannion, Rue E Branly,BP 30219, F-22302 Lannion, France
  • 4. Ataturk Univ, Dept Chem, TR-25240 Erzurum, Turkey

Description

Organic conjugated compounds containing various substituents 3-amino-2,4-dicyano-1-aryl-9H-fluorene and 1dicyanomethylene-2-aryl-indone derivatives were successfully obtained. Various routes and synthesis methods, such as one-pot, multi-step, and microwave irradiation (MWI), were explored for efficiency. Spectroscopic methods were used to characterize of the synthesized compounds. Furthermore (E)-2-(2-(anthracen-9-ylmethy-lene)-2,3-dihydro-1H-inden-1-ylidene) malononitrile (2b) compound which exhibited a crystal structure was also characterized via X-ray technique. The thermogravimetric analysis (TGA) was used to investigate the thermal stability. Finally, the photophysical properties of the synthesized compounds were also investigated using UV-vis and fluorescence.

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