Published January 1, 2013
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New phosphine oxide aziridinyl phosphonates as chiral Lewis bases for the Abramov-type phosphonylation of aldehydes
- 1. Middle E Tech Univ, Dept Chem, TR-06800 Ankara, Turkey
- 2. Dokuz Eylul Univ, Dept Phys, Buca Izmir, Turkey
Description
A series of Lewis bases were screened for Abramov-type phosphine additions to aldehydes. A novel phosphine oxide aziridinyl phosphonate POAP-A was found to be better than the others in forming the product in 96% yield and with 42% ee. The absolute configuration of the newly synthesized POAP Lewis bases was determined by single-crystal X-ray analysis. (C) 2013 Elsevier Ltd. All rights reserved.
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