1 Ocak 2015 Dergi makalesi Açık Erişim

Ertas, Ilknur Efecan; Gulcan, Mehmet; Bulut, Ahmet; Yurderi, Mehmet; Zahmakiran, Mehmet

Dublin Core

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  <dc:creator>Ertas, Ilknur Efecan</dc:creator>
  <dc:creator>Gulcan, Mehmet</dc:creator>
  <dc:creator>Bulut, Ahmet</dc:creator>
  <dc:creator>Yurderi, Mehmet</dc:creator>
  <dc:creator>Zahmakiran, Mehmet</dc:creator>
  <dc:date>2015-01-01</dc:date>
  <dc:description>Rhodium(0) nanoparticles stabilized by sulfonic acid functionalized metal-organic framework (Rh@SMIL-101) were prepared, for the first time, by using a direct cationic exchange approach and subsequent reduction with sodium borohydride at room temperature. The characterization of the resulting Rh@SMIL-101 material was done by using multi pronged analyses including ICP-OES, EA, P-XRD, XPS, DR-UV-vis, BFFEM, HRTEM, STEM-EDX and N2-adsorption-desorption technique, which revealed that the formation of rhodium(0) nanoparticles (2.35 +/- 0.9 nm) stabilized by the framework of S-MIL-101 by keeping the host framework intact (Rh@S-MIL-101). The catalytic performance of Rh@S-MIL-101 in terms of activity, selectivity and stability was demonstrated in the hydrogenation of phenol under mild conditions (at 50 degrees C and 5 bar initial H-2 pressure). We found that Rh@S-MIL-101 catalyst selectively hydrogenated phenol to cyclohexanone with high activity (initial TOF= 78 mol cyclohexanone/mol Rh x h) and selectivity (&gt;92%) at almost complete conversion (&gt;95%). Moreover, the resulting rhodium nanopartides were found to be highly stable against leaching and sintering, which makes Rh@S-MIL-101 reusable heterogeneous catalyst without losing of significant activity and selectivity. (C) 2015 Elsevier B.V. All rights reserved.</dc:description>
  <dc:identifier>https://aperta.ulakbim.gov.trrecord/80657</dc:identifier>
  <dc:identifier>oai:zenodo.org:80657</dc:identifier>
  <dc:rights>info:eu-repo/semantics/openAccess</dc:rights>
  <dc:rights>http://www.opendefinition.org/licenses/cc-by</dc:rights>
  <dc:source>JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL 410 209-220</dc:source>
  <dc:title>Rhodium nanoparticles stabilized by sulfonic acid functionalized metal-organic framework for the selective hydrogenation of phenol to cyclohexanone</dc:title>
  <dc:type>info:eu-repo/semantics/article</dc:type>
  <dc:type>publication-article</dc:type>
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