1 Ocak 2015 Dergi makalesi Açık Erişim

Ertas, Ilknur Efecan; Gulcan, Mehmet; Bulut, Ahmet; Yurderi, Mehmet; Zahmakiran, Mehmet

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        "affiliation": "Yuzuncu Yil Univ, Dept Chem, Nanomat & Catalysis NanoMatCat Res Lab, TR-65080 Van, Turkey", 
        "name": "Ertas, Ilknur Efecan"
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      {
        "affiliation": "Yuzuncu Yil Univ, Dept Chem, Nanomat & Catalysis NanoMatCat Res Lab, TR-65080 Van, Turkey", 
        "name": "Gulcan, Mehmet"
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      {
        "affiliation": "Yuzuncu Yil Univ, Dept Chem, Nanomat & Catalysis NanoMatCat Res Lab, TR-65080 Van, Turkey", 
        "name": "Bulut, Ahmet"
      }, 
      {
        "affiliation": "Yuzuncu Yil Univ, Dept Chem, Nanomat & Catalysis NanoMatCat Res Lab, TR-65080 Van, Turkey", 
        "name": "Yurderi, Mehmet"
      }, 
      {
        "affiliation": "Yuzuncu Yil Univ, Dept Chem, Nanomat & Catalysis NanoMatCat Res Lab, TR-65080 Van, Turkey", 
        "name": "Zahmakiran, Mehmet"
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    "description": "Rhodium(0) nanoparticles stabilized by sulfonic acid functionalized metal-organic framework (Rh@SMIL-101) were prepared, for the first time, by using a direct cationic exchange approach and subsequent reduction with sodium borohydride at room temperature. The characterization of the resulting Rh@SMIL-101 material was done by using multi pronged analyses including ICP-OES, EA, P-XRD, XPS, DR-UV-vis, BFFEM, HRTEM, STEM-EDX and N2-adsorption-desorption technique, which revealed that the formation of rhodium(0) nanoparticles (2.35 +/- 0.9 nm) stabilized by the framework of S-MIL-101 by keeping the host framework intact (Rh@S-MIL-101). The catalytic performance of Rh@S-MIL-101 in terms of activity, selectivity and stability was demonstrated in the hydrogenation of phenol under mild conditions (at 50 degrees C and 5 bar initial H-2 pressure). We found that Rh@S-MIL-101 catalyst selectively hydrogenated phenol to cyclohexanone with high activity (initial TOF= 78 mol cyclohexanone/mol Rh x h) and selectivity (>92%) at almost complete conversion (>95%). Moreover, the resulting rhodium nanopartides were found to be highly stable against leaching and sintering, which makes Rh@S-MIL-101 reusable heterogeneous catalyst without losing of significant activity and selectivity. (C) 2015 Elsevier B.V. All rights reserved.", 
    "doi": "10.1016/j.molcata.2015.09.025", 
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    "journal": {
      "pages": "209-220", 
      "title": "JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL", 
      "volume": "410"
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    "title": "Rhodium nanoparticles stabilized by sulfonic acid functionalized metal-organic framework for the selective hydrogenation of phenol to cyclohexanone"
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