Dergi makalesi Açık Erişim
Janos Balogh; Arpad Kuik; Laszlo Uerge; Ferenc Darvas; Jozsef Bakos; Rita Skoda-Foeldes
<?xml version='1.0' encoding='utf-8'?> <resource xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns="http://datacite.org/schema/kernel-4" xsi:schemaLocation="http://datacite.org/schema/kernel-4 http://schema.datacite.org/meta/kernel-4.1/metadata.xsd"> <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/43473</identifier> <creators> <creator> <creatorName>Janos Balogh</creatorName> <affiliation>Univ Pannonia, Inst Chem, Dept Inorgan Chem, H-8201 Veszprem, Hungary</affiliation> </creator> <creator> <creatorName>Arpad Kuik</creatorName> <affiliation>Univ Pannonia, Inst Chem, Dept Inorgan Chem, H-8201 Veszprem, Hungary</affiliation> </creator> <creator> <creatorName>Laszlo Uerge</creatorName> <affiliation>ThalesNano Inc, H-1031 Budapest, Hungary</affiliation> </creator> <creator> <creatorName>Ferenc Darvas</creatorName> <affiliation>ThalesNano Inc, H-1031 Budapest, Hungary</affiliation> </creator> <creator> <creatorName>Jozsef Bakos</creatorName> <affiliation>Univ Pannonia, Inst Chem, Dept Inorgan Chem, H-8201 Veszprem, Hungary</affiliation> </creator> <creator> <creatorName>Rita Skoda-Foeldes</creatorName> <affiliation>Univ Pannonia, Inst Chem, Dept Inorgan Chem, H-8201 Veszprem, Hungary</affiliation> </creator> </creators> <titles> <title>Double Carbonylation Of Iodobenzene In A Microfluidics-Based High Throughput Flow Reactor</title> </titles> <publisher>Aperta</publisher> <publicationYear>2009</publicationYear> <dates> <date dateType="Issued">2009-01-01</date> </dates> <resourceType resourceTypeGeneral="Text">Journal article</resourceType> <alternateIdentifiers> <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/43473</alternateIdentifier> </alternateIdentifiers> <relatedIdentifiers> <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1016/j.molcata.2008.11.035</relatedIdentifier> </relatedIdentifiers> <rightsList> <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights> <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights> </rightsList> <descriptions> <description descriptionType="Abstract">Double carbonylation of iodobenzene in the presence of amines were carried out effectively in a microfluidics-based flow reactor (X-Cube (TM)) of high throughput capability using immobilized Pd(PPh3)(4) catalyst. By the proper tuning of the reaction conditions alpha-ketoamides could be synthesized with 70-96% selectivities depending on the choice of the nucleophile. The highest yields of double carbonylation products were obtained at relatively low temperature (80 degrees C) and using DBU as the base with primary amines as the reaction partners. Imine formation was observed only at higher temperatures. (C) 2008 Elsevier B.V. All rights reserved.</description> </descriptions> </resource>
Görüntülenme | 93 |
İndirme | 16 |
Veri hacmi | 4.0 kB |
Tekil görüntülenme | 84 |
Tekil indirme | 16 |