1 Ocak 2022 Dergi makalesi Açık Erişim

Yavuz, Mustafa Selman; Citir, Murat

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{
  "@context": "https://schema.org/", 
  "@id": 230068, 
  "@type": "ScholarlyArticle", 
  "creator": [
    {
      "@type": "Person", 
      "name": "Yavuz, Mustafa Selman"
    }, 
    {
      "@type": "Person", 
      "name": "Citir, Murat"
    }
  ], 
  "datePublished": "2022-01-01", 
  "description": "In this study, we synthesized an aliphatic-aromatic regular network as a novel covalent organic networks called TEPN-1 (Thiol-ene Polymer Network) and TEPN-2 via thiol-ene chemistry. TEPN-1 and TEPN-2 were analyzed by FTIR, C-13-NMR, Brunauer-Emmett-Teller, thermogravimetric analysis and elemental analysis. Solvent uptake capacity of TEPN-1 and TEPN-2 was employed against 26 solvents which are frequently used in chemical industry. It is found that TEPN-1 has the highest swelling adsorption ratio with chloroform and DCM (13.7 and 11.5 g.g(-1), respectively), while TEPN-2 has 9.2 and 7.5 g.g(-1), respectively. Both TEPN-1 and TEPN-2 have very minimal water uptake (0.165 and 0.189 g.g(-1), respectively). TEPN-1 and TEPN-2 are efficient adsorbents for most of organic solvents including water-miscible organic solvents such as THF, dioxane and pyridine.", 
  "headline": "Highly efficient chlorinated solvent uptake by novel covalent organic networks via thiol-ene chemistry", 
  "identifier": 230068, 
  "image": "https://aperta.ulakbim.gov.tr/static/img/logo/aperta_logo_with_icon.svg", 
  "license": "http://www.opendefinition.org/licenses/cc-by", 
  "name": "Highly efficient chlorinated solvent uptake by novel covalent organic networks via thiol-ene chemistry", 
  "url": "https://aperta.ulakbim.gov.tr/record/230068"
}