1 Ocak 2022 Dergi makalesi Açık Erişim

Yavuz, Mustafa Selman; Citir, Murat

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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/230068</identifier>
  <creators>
    <creator>
      <creatorName>Yavuz, Mustafa Selman</creatorName>
      <givenName>Mustafa Selman</givenName>
      <familyName>Yavuz</familyName>
    </creator>
    <creator>
      <creatorName>Citir, Murat</creatorName>
      <givenName>Murat</givenName>
      <familyName>Citir</familyName>
    </creator>
  </creators>
  <titles>
    <title>Highly Efficient Chlorinated Solvent Uptake By Novel Covalent Organic Networks Via Thiol-Ene Chemistry</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2022</publicationYear>
  <dates>
    <date dateType="Issued">2022-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/230068</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1007/s00289-021-03809-4</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">In this study, we synthesized an aliphatic-aromatic regular network as a novel covalent organic networks called TEPN-1 (Thiol-ene Polymer Network) and TEPN-2 via thiol-ene chemistry. TEPN-1 and TEPN-2 were analyzed by FTIR, C-13-NMR, Brunauer-Emmett-Teller, thermogravimetric analysis and elemental analysis. Solvent uptake capacity of TEPN-1 and TEPN-2 was employed against 26 solvents which are frequently used in chemical industry. It is found that TEPN-1 has the highest swelling adsorption ratio with chloroform and DCM (13.7 and 11.5 g.g(-1), respectively), while TEPN-2 has 9.2 and 7.5 g.g(-1), respectively. Both TEPN-1 and TEPN-2 have very minimal water uptake (0.165 and 0.189 g.g(-1), respectively). TEPN-1 and TEPN-2 are efficient adsorbents for most of organic solvents including water-miscible organic solvents such as THF, dioxane and pyridine.</description>
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