Dergi makalesi Açık Erişim
Yavuz, Mustafa Selman; Citir, Murat
{ "DOI": "10.1007/s00289-021-03809-4", "abstract": "In this study, we synthesized an aliphatic-aromatic regular network as a novel covalent organic networks called TEPN-1 (Thiol-ene Polymer Network) and TEPN-2 via thiol-ene chemistry. TEPN-1 and TEPN-2 were analyzed by FTIR, C-13-NMR, Brunauer-Emmett-Teller, thermogravimetric analysis and elemental analysis. Solvent uptake capacity of TEPN-1 and TEPN-2 was employed against 26 solvents which are frequently used in chemical industry. It is found that TEPN-1 has the highest swelling adsorption ratio with chloroform and DCM (13.7 and 11.5 g.g(-1), respectively), while TEPN-2 has 9.2 and 7.5 g.g(-1), respectively. Both TEPN-1 and TEPN-2 have very minimal water uptake (0.165 and 0.189 g.g(-1), respectively). TEPN-1 and TEPN-2 are efficient adsorbents for most of organic solvents including water-miscible organic solvents such as THF, dioxane and pyridine.", "author": [ { "family": "Yavuz", "given": " Mustafa Selman" }, { "family": "Citir", "given": " Murat" } ], "container_title": "POLYMER BULLETIN", "id": "230068", "issue": "8", "issued": { "date-parts": [ [ 2022, 1, 1 ] ] }, "page": "6343-6356", "title": "Highly efficient chlorinated solvent uptake by novel covalent organic networks via thiol-ene chemistry", "type": "article-journal", "volume": "79" }
Görüntülenme | 18 |
İndirme | 4 |
Veri hacmi | 676 Bytes |
Tekil görüntülenme | 17 |
Tekil indirme | 4 |