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Highly efficient chlorinated solvent uptake by novel covalent organic networks via thiol-ene chemistry

Yavuz, Mustafa Selman; Citir, Murat


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{
  "DOI": "10.1007/s00289-021-03809-4", 
  "abstract": "In this study, we synthesized an aliphatic-aromatic regular network as a novel covalent organic networks called TEPN-1 (Thiol-ene Polymer Network) and TEPN-2 via thiol-ene chemistry. TEPN-1 and TEPN-2 were analyzed by FTIR, C-13-NMR, Brunauer-Emmett-Teller, thermogravimetric analysis and elemental analysis. Solvent uptake capacity of TEPN-1 and TEPN-2 was employed against 26 solvents which are frequently used in chemical industry. It is found that TEPN-1 has the highest swelling adsorption ratio with chloroform and DCM (13.7 and 11.5 g.g(-1), respectively), while TEPN-2 has 9.2 and 7.5 g.g(-1), respectively. Both TEPN-1 and TEPN-2 have very minimal water uptake (0.165 and 0.189 g.g(-1), respectively). TEPN-1 and TEPN-2 are efficient adsorbents for most of organic solvents including water-miscible organic solvents such as THF, dioxane and pyridine.", 
  "author": [
    {
      "family": "Yavuz", 
      "given": " Mustafa Selman"
    }, 
    {
      "family": "Citir", 
      "given": " Murat"
    }
  ], 
  "container_title": "POLYMER BULLETIN", 
  "id": "230068", 
  "issue": "8", 
  "issued": {
    "date-parts": [
      [
        2022, 
        1, 
        1
      ]
    ]
  }, 
  "page": "6343-6356", 
  "title": "Highly efficient chlorinated solvent uptake by novel covalent organic networks via thiol-ene chemistry", 
  "type": "article-journal", 
  "volume": "79"
}
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