1 Ocak 2013 Dergi makalesi Açık Erişim

Biyiklioglu, Zekeriya; Saka, Ece Tugba; Gokce, Serpil; Kantekin, Halit

DataCite XML

<?xml version='1.0' encoding='utf-8'?>
<resource xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns="http://datacite.org/schema/kernel-4" xsi:schemaLocation="http://datacite.org/schema/kernel-4 http://schema.datacite.org/meta/kernel-4.1/metadata.xsd">
  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/13865</identifier>
  <creators>
    <creator>
      <creatorName>Biyiklioglu, Zekeriya</creatorName>
      <givenName>Zekeriya</givenName>
      <familyName>Biyiklioglu</familyName>
      <affiliation>Karadeniz Tech Univ, Dept Chem, Fac Sci, TR-61080 Trabzon, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Saka, Ece Tugba</creatorName>
      <givenName>Ece Tugba</givenName>
      <familyName>Saka</familyName>
      <affiliation>Karadeniz Tech Univ, Dept Chem, Fac Sci, TR-61080 Trabzon, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Gokce, Serpil</creatorName>
      <givenName>Serpil</givenName>
      <familyName>Gokce</familyName>
      <affiliation>Karadeniz Tech Univ, Dept Chem, Fac Sci, TR-61080 Trabzon, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Kantekin, Halit</creatorName>
      <givenName>Halit</givenName>
      <familyName>Kantekin</familyName>
      <affiliation>Karadeniz Tech Univ, Dept Chem, Fac Sci, TR-61080 Trabzon, Turkey</affiliation>
    </creator>
  </creators>
  <titles>
    <title>Synthesis, Characterization And Investigation Of Homogeneous Oxidation Activities Of Peripherally Tetra-Substituted Co(Ii) And Fe(Ii) Phthalocyanines: Oxidation Of Cyclohexene</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2013</publicationYear>
  <dates>
    <date dateType="Issued">2013-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/13865</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1016/j.molcata.2013.06.009</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">The synthesis and characterization of novel peripherally tetra-substituted iron(II) 4 and cobalt(II) 5 phthalocyanines are described for the first time in this study. All the new compounds are characterized by a combination of IR, H-1 and C-13 NMR, mass and UV-vis spectroscopy techniques. Complexes 4 and 5 served as catalyst for the oxidation of cyclohexene using different types of oxidants, such as tert-butyl hydroperoxide (TBHP), m-chloroperoxybenzoic acid (m-CPBA), aerobic oxygen and hydrogen peroxide (H2O2). During the oxidation process the products formed are 2-cyclohexene-1-ol, 2-cyclohexene-1-one and cyclohexene oxide. The selectivity for 2-cyclohexene-1-ol is favored when iron(II) and cobalt(II) phthalocyanine catalysts are employed. The higher conversion is obtained as catalyst iron(II) phthalocyanine (96%). TBHP was determined as the successful oxidant with the minimum demolition of the catalyst, superior selectivity and conversion in the oxidation products. (c) 2013 Elsevier B.V. All rights reserved.</description>
  </descriptions>
</resource>