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Neutral cyclic sp(2)-sp(3)and sp(3)-sp(3)diboranes from N, N '-dicyclohexylcarbodiimide insertion into 1,2-dichlorodiboranes(4)

2020    Firinci, Erkan; Firinci, Rukiye; Sevincek, Resul; Aygun, Muhittin; Sahin, Yuksel

We report the synthesis and structural characterization of new neutral cyclic sp(2)-sp(3)and sp(3)-sp(3)diboranes from the reaction ofN,N '-dicyclohexylcarbodiimide with 1,2-dichlorodiboranes(4) at room temperature. The present study is the first example of an insertion reaction of carbodiimide into diborane(4).